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Preheat oven to 400°F. Place potato rounds in one layer across a couple of non-stick cookie sheets. Drizzle with olive oil (or spray with cooking spray), salt, and pepper. Roast 20 minutes or until browned and crispy, flipping halfway through.
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While the potatoes cook, heat 1 tsp olive oil on medium high until hot. Add the peppers and cook, stirring occasionally, 2 to 3 minutes, or until browned and softened; season with salt and pepper. Set aside.
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Add 1 tsp olive oil, if needed. Add the garlic and shallot; season with salt and pepper. Cook, stirring frequently, 30 seconds to 1 minute, or until softened and fragrant. Add the corn; season with salt and pepper. Cook, stirring occasionally, 2 to 3 minutes, or until lightly browned and slightly softened. Add half the oregano and cook, stirring occasionally, 30 seconds to 1 minute, or until fragrant.
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Combine potatoes, corn, and peppers, and set aside.
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Pat the cod fillets dry with paper towels. Season with salt and pepper on both sides. In the same pan, heat butter and 1 tsp of olive oil on medium-high until melted and hot. Add the seasoned fillets and cook 2 to 3 minutes on the first side, or until browned. Flip and slowly add the vinegar. Cook, occasionally spooning the sauce over the fillets, 1 to 2 minutes, or until thoroughly coated and cooked through. Transfer to a plate, leaving the sauce in the pan.
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Drizzle sauce over the cooked veggies. Serve cod over top and garnish with oregano.